Heavy Metals

Table 4.13 lists the most commonly encountered pollutants in water; however, in many industrial applications various heavy metals are frequently combined in the process discharge.

Some heavy metals are essential to life at low concentrations but are dan­gerous to animal and plant life in higher concentrations. Generally, it is the free metal ion that is the most toxic; however, with Hg and Sn certain organic forms have a greater toxicity.

The WHO, the CEN, and the Environmental Protection Agency in the United States specify the maximum permissible concentrations of these metals and other pollutants in the environment.

Due to the many variables involved, no attempt is made at this stage to cover the various methods used to remove these pollutants before the water is released into the environment. Table 4.14 lists the common heavy metals in water.

TABLE 4.14 Heavy Metals

Constituent

Chemical

Formula

Problems caused

Antimony

Sb

Moderately toxic

Arsenic

As

Highly toxic, corrosive, carcinogen

Beryllium

Be

High toxicity, long-term, effects

Cadmium

Cd

Highly toxic, carcinogen

Chromium

Cr

Compounds may be highly toxic

Cobalt

Co

Moderate toxic

Copper

Cu

Highly toxic

Lead

Pb

A cumulative poison

Mercury

Hg

Very highly toxic

Molybdenum

Mo

Compounds are highly toxic

Nickel

Ni

Highly toxic, carcinogenic

Selenium

Se

Highly toxic

Silver

Ag

Low toxicity

Tellurium

Te

Highly toxic

Thallium

ТІ

Sulfates highly toxic

Hr,

Sn

Irritation of skin, eyes, lungs, and stomach

Titanium

Ті

Chlorides are moderately toxic

Uranium

U

Toxic, insoluble in water

Vanadium

Va

Oxides and chlorides have a high tox­icity

Zinc

Zn

Moderately toxic, carcinogenic

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